Inter-relationships of MnO₂ precipitation, siderophore-Mn complex formation, siderophore degradation, and iron limitation in Mn-oxidizing bacterial cultures     

Dorothy L. Parker  Takami Morita  Rebecca Verity  James K. McCarthy 《Geochimica et cosmochimica acta》2007,71(23):5672-5683

To examine the pathways that form Mn^(III) and Mn^(IV) in the Mn^(II)-oxidizing bacterial strains Pseudomonas putida GB-1 and MnB1, and to test whether the siderophore pyoverdine (PVD) inhibits Mn^(IV)O₂ formation, cultures were subjected to various protocols at known concentrations of iron and PVD. Depending on growth conditions, P. putida produced one of two oxidized Mn species - either soluble PVD-Mn^(III) complex or insoluble Mn^(IV)O₂ minerals - but not both simultaneously. PVD-Mn^(III) was present, and MnO₂ precipitation was inhibited, both in iron-limited cultures that had synthesized 26-50 μM PVD and in iron-replete (non-PVD-producing) cultures that were supplemented with 10-550 μM purified PVD. PVD-Mn^(III) arose by predominantly ligand-mediated air oxidation of Mn^(II) in the presence of PVD, based on the following evidence: (a) yields and rates of this reaction were similar in sterile media and in cultures, and (b) GB-1 mutants deficient in enzymatic Mn oxidation produced PVD-Mn^(III) as efficiently as wild type. Only wild type, however, could degrade PVD-Mn^(III), a process linked to the production of both MnO₂ and an altered PVD with absorbance and fluorescence spectra markedly different from those of either PVD or PVD-Mn^(III). Two conditions, the presence of bioavailable iron and the absence of PVD at concentrations exceeding those of Mn, both had to be satisfied for MnO₂ to appear. These results suggest that P. putida cultures produce soluble Mn^(III) or MnO₂ by different and mutually inhibitory pathways: enzymatic catalysis yielding MnO₂ under iron sufficiency or PVD-promoted oxidation yielding PVD-Mn^(III) under iron limitation. Since PVD-producing Pseudomonas species are environmentally prevalent Mn oxidizers, these data predict influences of iron (via PVD-Mn^(III) versus MnO₂) on the global oxidation/reduction cycling of various pollutants, recalcitrant organic matter, and elements such as C, S, N, Cr, U, and Mn.  相似文献   

Impact of storm runoff from tropical watersheds on coastal water quality and productivity     

E. Heinen De Carlo  Daniel J. HooverCharles W. Young  Rebecca S. HooverFred T. Mackenzie 《Applied Geochemistry》2007

Storm runoff in the steep watersheds in Hawaii leads to sediment and freshwater pulses to coastal waters that quickly affect nearshore water quality. This is particularly true in semi-enclosed embayments, such as Kaneohe Bay, Oahu, where water has a relatively long residence time compared to more open coastal areas of the islands. In this paper the authors discuss water quality and productivity in Kaneohe Bay after back-to-back rain events in late November and early December 2003, following a particularly dry summer. The short-term biogeochemical response of coastal waters and the ecosystem to runoff and physical forcing was evaluated through a combination of continuous in situ measurements and adaptive synoptic sampling carried out on a variety of temporal and spatial scales.  相似文献   

Reconciling feminist theory and gendered resource management in Indonesia     

Rebecca Elmhirst 《Area》1998,30(3):225-235

Summary This paper considers the difficulties in reconciling a fluid and ambiguous conceptualization of gender difference with policy-based efforts to define women as 'target groups' in development interventions. The issue is explored with reference to gender issues in a transmigration resettlement area in Indonesia, where the instability of gender identities is particularly marked, and where gendered resource use and control are particularly blurred.  相似文献   

On the occurrence and origin of anthropogenic radionuclides found in a fragment of the Chelyabinsk (LL5) meteorite          下载免费PDF全文

Rebecca Querfeld  Mohammad R. Tanha  Lars Heyer  Franz Renz  Georg Guggenberger  Franz Brandstätter  Ludovic Ferrière  Christian Koeberl  Georg Steinhauser 《Meteoritics & planetary science》2017,52(6):1244-1250

A piece of the 2013 Chelyabinsk meteorite was investigated for its content of anthropogenic radionuclides. In addition to traces of cesium‐137 that had been previously reported for this particular fragment, we found an unusually high amount of strontium‐90, which indicates that the source of this contamination was the Kyshtym accident (1957). A high Sr‐90/Cs‐137 activity ratio is characteristic for Kyshtym‐derived contaminations. Based on the cesium‐137 content in the soil from the finding site, it is estimated that the fragment was contaminated with soil particles in the milligram range upon impact. Investigation of the soil revealed very unusual ferromagnetic characteristics and an iron‐rich chemical composition. Mössbauer spectroscopy indicated the presence of steel components in this soil, suggesting that the investigated meteorite fragment was found in an industrial dumping site rather than natural soil.  相似文献   

A review of marine mammal,sea turtle and seabird bycatch in USA fisheries and the role of policy in shaping management     

Jeffrey E. Moore  Bryan P. Wallace  Rebecca L. Lewison  Ramúnas Žydelis  Tara M. Cox  Larry B. Crowder 《Marine Policy》2009

This paper reviews the available information (observer programs, estimates, statutes, regulations) for bycatch of marine mammals, sea turtles, and seabirds in fisheries of the United States. Goals of the review were to evaluate the state of knowledge of bycatch and the role of existing protective legislation in shaping bycatch management for different taxa. Pressing issues are identified, as well as knowledge gaps and policy limitations that hinder multi-species bycatch reduction. The USA has made important progress toward reducing bycatch in its fisheries, but the efficacy of its management has been limited somewhat by a focus on taxon- and fishery-specific regulation and the lack of consistent mandate across taxa for taking a cumulative perspective on bycatch. Applying consistent criteria across taxa for setting bycatch limits (e.g., extending the approach used for marine mammals to sea turtles and seabirds) would be the first step in a multi-species approach to bycatch reduction. A population-based multi-species multi-gear approach to bycatch would help identify priority areas where resources are needed most and can be used most effectively.  相似文献   

Alignment and precession of a black hole with a warped accretion disc     

Rebecca G. Martin  J. E. Pringle  Christopher A. Tout 《Monthly notices of the Royal Astronomical Society》2007,381(4):1617-1624

We consider the shape of an accretion disc whose outer regions are misaligned with the spin axis of a central black hole and calculate the steady state form of the warped disc in the case where the viscosity and surface densities are power laws in the distance from the central black hole. We discuss the shape of the resulting disc in both the frame of the black hole and that of the outer disc. We note that some parts of the disc and also any companion star maybe shadowed from the central regions by the warp. We compute the torque on the black hole caused by the Lense–Thirring precession, and hence compute the alignment and precession time-scales. We generalize the case with viscosity and hence surface density independent of radius to more realistic density distributions for which the surface density is a decreasing function of radius. We find that the alignment time-scale does not change greatly but the precession time-scale is more sensitive. We also determine the effect on this time-scale if we truncate the disc. For a given truncation radius, the time-scales are less affected for more sharply falling density distributions.  相似文献   

Sea-level rise research and dialogue in North Carolina: Creating windows for policy change     

Benjamin Poulter  Rebecca L. Feldman  Mark M. Brinson  Benjamin P. Horton  Michael K. Orbach  Samuel H. Pearsall  Enrique Reyes  Stanley R. Riggs  John C. Whitehead 《Ocean & Coastal Management》2009,52(3-4):147-153

Coastal areas are among the world's most vulnerable landscapes to impacts related to climate change, including inundation from sea-level rise (SLR), increased exposure to shoreline erosion, and greater frequency and intensity of storms. The status of research on the physical, ecological, and socio-economic effects of vulnerability to SLR and progress toward planning for its consequences varies from region to region worldwide. Here, we synthesize the results of three decades of SLR research and the development of coastal management policies in North Carolina, USA. We identify the major factors responsible for opening new policy ‘windows’ that address SLR, including how stakeholders have developed an increased understanding of the risks, the extent of public dialogue about potential response strategies, and advances in political receptivity to policy change. Research and policy progress in North Carolina continue to provide a model for other regions to help guide and evaluate the development of coastal policies.  相似文献   

Hyperspectral mapping of alteration assemblages within a hydrothermal vug at the Haughton impact structure,Canada          下载免费PDF全文

Rebecca N. Greenberger  John F. Mustard  Gordon R. Osinski  Livio L. Tornabene  Alexandra J. Pontefract  Cassandra L. Marion  Roberta L. Flemming  Janette H. Wilson  Edward A. Cloutis 《Meteoritics & planetary science》2016,51(12):2274-2292

Meteorite impacts on Earth and Mars can generate hydrothermal systems that alter the primary mineralogies of rocks and provide suitable environments for microbial colonization. We investigate a calcite–marcasite‐bearing vug at the ~23 km diameter Haughton impact structure, Devon Island, Nunavut, Canada, using imaging spectroscopy of the outcrop in the field (0.65–1.1 μm) and samples in the laboratory (0.4–2.5 μm), point spectroscopy (0.35–2.5 μm), major element chemistry, and X‐ray diffraction analyses. The mineral assemblages mapped at the outcrop include marcasite; marcasite with minor gypsum and jarosite; fibroferrite and copiapite with minor gypsum and melanterite; gypsum, Fe³⁺ oxides, and jarosite; and calcite, gypsum, clay, microcline, and quartz. Hyperspectral mapping of alteration phases shows spatial patterns that illuminate changes in alteration conditions and formation of specific mineral phases. Marcasite formed from the postimpact hydrothermal system under reducing conditions, while subsequent weathering oxidized the marcasite at low temperatures and water/rock ratios. The acidic fluids resulting from the oxidation collected on flat‐lying portions of the outcrop, precipitating fibroferrite + copiapite. That assemblage then likely dissolved, and the changing chemistry and pH resulting from interaction with the calcite‐rich host rock formed gypsum‐bearing red coatings. These results have implications for understanding water–rock interactions and habitabilities at this site and on Mars.  相似文献   

Scientific advocacy,environmental interest groups,and climate change: are climate skeptic portrayals of climate scientists as biased accurate?     

Rebecca Bromley-Trujillo  James W. Stoutenborough  Arnold Vedlitz 《Climatic change》2015,131(4):607-620

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A new chronological framework for Middle and Upper Pleistocene landscape evolution in the Sussex/Hampshire Coastal Corridor, UK     

Martin R. Bates  Rebecca M. Briant  Jean-Luc Schwenninger 《Proceedings of the Geologists' Association. Geologists' Association》2010,121(4):369-392

The unique Middle and Late Pleistocene sedimentary record preserved along the Sussex/Hampshire Coastal Corridor between Romsey and Brighton contains a wealth of deposits including highstand marine sediments associated with a variety of different aged beaches, fluvial sediments associated with rivers crossing the coastal plain and cold stage deposits accumulating above the marine and fluvial sediments. Although quarrying activity has been extensive across much of the area it has been undertaken in flooded workings due to the high level of the watertable. Consequently little is known in detail about the sequences except where they outcrop on the foreshore around the coast. This paper examines recent work from the lower coastal plain using a multi-disciplinary approach these deposits to elucidate the age of the sequences and their associated environments of deposition.OSL dates from two of the beaches, the Aldingbourne and Brighton/Norton Beaches, place both within MIS 7. Although these OSL dates cannot differentiate between sub-stages within MIS 7, coupling these results with inferences from local geography, lithology and contained microfossils it is clear that the beaches belong to two different phases within MIS 7. These two beaches are clearly divided by a major phase of erosion and downcutting associated with a fall in sea-level. Fluvial sediments from Solent Terrace 2 and Arun Terrace 4 also date within MIS 7 and are tentatively ascribed to the downcutting event between the beaches. Together this information allows us to propose, for the first time, a robust independently dated framework for the lower parts of the coastal plain integrating for the first time the marine and terrestrial record.  相似文献